Mechanical Properties of Ag Nanoparticle Thin Films Synthesized by Supersonic Cluster Beam Deposition

Emanuele Cavaliere, Claudio Giannetti, Gabriele Ferrini, Luca Gavioli, Francesco Banfi, Simone Peli, Giulio Benetti, Marco Gandolfi, Mirco Chiodi, Claudia Cancellieri

Risultato della ricerca: Contributo in rivistaArticolo in rivistapeer review

24 Citazioni (Scopus)

Abstract

The morphological and mechanical properties of nanoparticles-based ultrathin Ag films, synthesized by supersonic cluster beam deposition over a sapphire substrate, are unveiled exploiting ultrafast optoacoustic, atomic force microscopy, X-ray photoelectron spectroscopies, and X-ray diffraction techniques. The films, with thicknesses in the 10–50 nm range, have a porous structure composed of metallic Ag nanoparticles with a crystalline structure and average diameter of 6 nm. The films acoustic modes are in the hypersonic frequency range, the thinner films frequencies exceeding 100 GHz. The acoustic spectra are well accounted for modeling the nanoparticles film as an effective continuous medium. The modes quality factors show the existence of acoustically quasi-dark and bright states. The film effective density and effective elastic stiffness constants are respectively 0.8 and 0.5 that of bulk Ag. The present results are relevant in view of applications for optoacoustic transducers in the hypersonic frequency range, for optical coatings technology and for the production of mechanically stable bactericidal coatings.
Lingua originaleEnglish
pagine (da-a)4673-4681
Numero di pagine9
RivistaJOURNAL OF PHYSICAL CHEMISTRY. C
Volume120
DOI
Stato di pubblicazionePubblicato - 2016

Keywords

  • nanoparticles
  • supersonic cluster beam deposition

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