Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of α-allyl-β-ketoesters

Sandro Cacchi; Giancarlo Fabrizi; Antonella Goggiamani; Antonia Iazzetti; David Madec; Giovanni Poli; Guillaume Prestat

doi:10.1039/c1ob06593a

Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of α-allyl-β-ketoesters

Sandro Cacchi^*
, Giancarlo Fabrizi
, Antonella Goggiamani
, Antonia Iazzetti
, David Madec
, Giovanni Poli
, Guillaume Prestat

^*Autore corrispondente per questo lavoro

University of Rome La Sapienza
Université Paul Sabatier Toulouse III
Sorbonne Université

Risultato della ricerca: Contributo in rivista › Articolo

Abstract

The palladium-catalyzed reaction of (hetero)aryl bromides, chlorides, and nonaflates with α-allyl-β-ketoesters provides ready efficient access to functionalized 2,3-dihydrofurans. The reaction tolerates several useful substituents including chloro, fluoro, ether, ketone, ester, cyano, and nitro groups. © The Royal Society of Chemistry 2011.

Lingua originale	Inglese
pagine (da-a)	8233-8236
Numero di pagine	4
Rivista	ORGANIC & BIOMOLECULAR CHEMISTRY
Volume	9
DOI	https://doi.org/10.1039/c1ob06593a
Stato di pubblicazione	Pubblicato - 2011

Keywords

Catalysis
Esters
Furans
Ketones
Molecular Structure
Palladium
Stereoisomerism

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10.1039/c1ob06593a

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title = "Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of α-allyl-β-ketoesters",

abstract = "The palladium-catalyzed reaction of (hetero)aryl bromides, chlorides, and nonaflates with α-allyl-β-ketoesters provides ready efficient access to functionalized 2,3-dihydrofurans. The reaction tolerates several useful substituents including chloro, fluoro, ether, ketone, ester, cyano, and nitro groups. {\textcopyright} The Royal Society of Chemistry 2011.",

keywords = "Catalysis, Esters, Furans, Ketones, Molecular Structure, Palladium, Stereoisomerism, Catalysis, Esters, Furans, Ketones, Molecular Structure, Palladium, Stereoisomerism",

author = "Sandro Cacchi and Giancarlo Fabrizi and Antonella Goggiamani and Antonia Iazzetti and David Madec and Giovanni Poli and Guillaume Prestat",

year = "2011",

doi = "10.1039/c1ob06593a",

language = "English",

volume = "9",

pages = "8233--8236",

journal = "ORGANIC \& BIOMOLECULAR CHEMISTRY",

issn = "1477-0520",

publisher = "Royal Society of Chemistry:Thomas Graham House, Science Park, Cambridge CB4 0WF United Kingdom:011 44 1223 432360, EMAIL: [email protected], INTERNET: http://www.rsc.org, http://www.chensoc.org, Fax: 011 44 1223 423429",

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TY - JOUR

T1 - Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of α-allyl-β-ketoesters

AU - Cacchi, Sandro

AU - Fabrizi, Giancarlo

AU - Goggiamani, Antonella

AU - Iazzetti, Antonia

AU - Madec, David

AU - Poli, Giovanni

AU - Prestat, Guillaume

PY - 2011

Y1 - 2011

N2 - The palladium-catalyzed reaction of (hetero)aryl bromides, chlorides, and nonaflates with α-allyl-β-ketoesters provides ready efficient access to functionalized 2,3-dihydrofurans. The reaction tolerates several useful substituents including chloro, fluoro, ether, ketone, ester, cyano, and nitro groups. © The Royal Society of Chemistry 2011.

AB - The palladium-catalyzed reaction of (hetero)aryl bromides, chlorides, and nonaflates with α-allyl-β-ketoesters provides ready efficient access to functionalized 2,3-dihydrofurans. The reaction tolerates several useful substituents including chloro, fluoro, ether, ketone, ester, cyano, and nitro groups. © The Royal Society of Chemistry 2011.

KW - Catalysis

KW - Esters

KW - Furans

KW - Ketones

KW - Molecular Structure

KW - Palladium

KW - Stereoisomerism

KW - Catalysis

KW - Esters

KW - Furans

KW - Ketones

KW - Molecular Structure

KW - Palladium

KW - Stereoisomerism

UR - http://hdl.handle.net/10807/200796

U2 - 10.1039/c1ob06593a

DO - 10.1039/c1ob06593a

M3 - Article

SN - 1477-0520

VL - 9

SP - 8233

EP - 8236

JO - ORGANIC & BIOMOLECULAR CHEMISTRY

JF - ORGANIC & BIOMOLECULAR CHEMISTRY

ER -

Functionalized 2,3-dihydrofurans via palladium-catalyzed oxyarylation of α-allyl-β-ketoesters

Abstract

Keywords

Accesso al documento

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