Determination of Sb(III) and Sb(V) by HPLC—Online isotopic dilution—ICP \{MS\}

Maria Chiara Fontanella; Gian Maria Beone

doi:http://dx.doi.org/10.1016/j.mex.2015.12.001

Determination of Sb(III) and Sb(V) by HPLC—Online isotopic dilution—ICP \{MS\}

Maria Chiara Fontanella, Gian Maria Beone

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

Abstract This work provides a method with application of valid techniques to extract and determinate inorganic species of antimony (Sb) for water. The procedure involves• the simultaneous accumulation of Sb(III) and Sb(V) on passive samplers like Diffusive Gradient in Thin Films (DGT) with iron (Fe) oxide gel, eliminating the risk of speciation changes due to transport and storage; • application of less concentrated acid (50 mM Na2EDTA) for elution and preservation of Sb species from \{DGT\} resin; • subsequent analytical determination of inorganic species with High Performance Liquid Chromatography–Isotopic Dilution–Inductively Coupled Plasma Mass Spectrometer (HPLC-ID-ICP MS) based on determination of the isotope ratio (123Sb/121Sb) of isotopes in the samples after spiking with 123Sb enriched standard solution, reducing the effect of signal drift and matrix effect on the final value.

Original language	English
Pages (from-to)	102-109
Number of pages	8
Journal	METHODSX (AMSTERDAM)
Volume	3
DOIs	https://doi.org/10.1016/j.mex.2015.12.001
Publication status	Published - 2016

Keywords

Diffusive gradient in thin film
Trivalent antimony

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http://dx.doi.org/10.1016/j.mex.2015.12.001

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@article{6dbadbd054d44ce3b82fc0b499edeb33,

title = "Determination of Sb(III) and Sb(V) by HPLC—Online isotopic dilution—ICP \{MS\}",

abstract = "Abstract This work provides a method with application of valid techniques to extract and determinate inorganic species of antimony (Sb) for water. The procedure involves• the simultaneous accumulation of Sb(III) and Sb(V) on passive samplers like Diffusive Gradient in Thin Films (DGT) with iron (Fe) oxide gel, eliminating the risk of speciation changes due to transport and storage; • application of less concentrated acid (50 mM Na2EDTA) for elution and preservation of Sb species from \{DGT\} resin; • subsequent analytical determination of inorganic species with High Performance Liquid Chromatography–Isotopic Dilution–Inductively Coupled Plasma Mass Spectrometer (HPLC-ID-ICP MS) based on determination of the isotope ratio (123Sb/121Sb) of isotopes in the samples after spiking with 123Sb enriched standard solution, reducing the effect of signal drift and matrix effect on the final value.",

keywords = "Diffusive gradient in thin film, Trivalent antimony, Diffusive gradient in thin film, Trivalent antimony",

author = "Fontanella, {Maria Chiara} and Beone, {Gian Maria}",

year = "2016",

doi = "http://dx.doi.org/10.1016/j.mex.2015.12.001",

language = "English",

volume = "3",

pages = "102--109",

journal = "MethodsX",

issn = "2215-0161",

publisher = "Amsterdam : Elsevier B.V.",

}

TY - JOUR

T1 - Determination of Sb(III) and Sb(V) by HPLC—Online isotopic dilution—ICP \{MS\}

AU - Fontanella, Maria Chiara

AU - Beone, Gian Maria

PY - 2016

Y1 - 2016

N2 - Abstract This work provides a method with application of valid techniques to extract and determinate inorganic species of antimony (Sb) for water. The procedure involves• the simultaneous accumulation of Sb(III) and Sb(V) on passive samplers like Diffusive Gradient in Thin Films (DGT) with iron (Fe) oxide gel, eliminating the risk of speciation changes due to transport and storage; • application of less concentrated acid (50 mM Na2EDTA) for elution and preservation of Sb species from \{DGT\} resin; • subsequent analytical determination of inorganic species with High Performance Liquid Chromatography–Isotopic Dilution–Inductively Coupled Plasma Mass Spectrometer (HPLC-ID-ICP MS) based on determination of the isotope ratio (123Sb/121Sb) of isotopes in the samples after spiking with 123Sb enriched standard solution, reducing the effect of signal drift and matrix effect on the final value.

AB - Abstract This work provides a method with application of valid techniques to extract and determinate inorganic species of antimony (Sb) for water. The procedure involves• the simultaneous accumulation of Sb(III) and Sb(V) on passive samplers like Diffusive Gradient in Thin Films (DGT) with iron (Fe) oxide gel, eliminating the risk of speciation changes due to transport and storage; • application of less concentrated acid (50 mM Na2EDTA) for elution and preservation of Sb species from \{DGT\} resin; • subsequent analytical determination of inorganic species with High Performance Liquid Chromatography–Isotopic Dilution–Inductively Coupled Plasma Mass Spectrometer (HPLC-ID-ICP MS) based on determination of the isotope ratio (123Sb/121Sb) of isotopes in the samples after spiking with 123Sb enriched standard solution, reducing the effect of signal drift and matrix effect on the final value.

KW - Diffusive gradient in thin film

KW - Trivalent antimony

KW - Diffusive gradient in thin film

KW - Trivalent antimony

UR - http://hdl.handle.net/10807/71083

UR - http://www.sciencedirect.com/science/article/pii/s2215016115000655

U2 - http://dx.doi.org/10.1016/j.mex.2015.12.001

DO - http://dx.doi.org/10.1016/j.mex.2015.12.001

M3 - Article

SN - 2215-0161

VL - 3

SP - 102

EP - 109

JO - MethodsX

JF - MethodsX

ER -

Determination of Sb(III) and Sb(V) by HPLC—Online isotopic dilution—ICP \{MS\}

Abstract

Keywords

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